Octanoic Acid → HCID 18695150, compound

HRID 2417558Notes

Reaction equation

HRID 2417558 reaction equation
[Sb:1].[C:2]([OH:11])(=[O:10])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH3:9].CCCCCCC.[N+]([O-])(O)=O>O>[C:2]([O-:11])(=[O:10])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH3:9].[Sb+3:1].[C:2]([O-:11])(=[O:10])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH3:9].[C:2]([O-:11])(=[O:10])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH3:9]

Participants

6

Reactant 4

HCID 379Octanoic AcidHCID 944Nitric Acid2×HCID 8900HeptaneHCID 5354495Antimony

Product 1

HCID 18695150HCID 18695150, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

The procedure of Example 5 was followed using a reaction mixture composed of 1 g. of antimony metal, 50 g. of octanoic acid, 20 ml. of n-heptane and 0.45 g. of 70% aqueous HNO3. The reaction temperature was about 120° C. and the HNO3 was added dropwise as in Example 5. The water of reaction was removed azeotropically with n-heptane and was collected in the Dean-Stark tube as in Example 6. The clear solution which resulted was concentrated and dried to produce a quantitative solid residue of Antimony(III) octanoate which had an UV-visible spectrum band at about 297 nm.

Workup

  1. customwas about 120° C.
  2. customwas removed azeotropically with n-heptane
  3. customwas collected in the Dean-Stark tube as in Example 6
  4. customThe clear solution which resulted
  5. concentrationwas concentrated
  6. customdried

Sources & evidence

ORD record
ord-1f8a45c2b2cc47ca859e2f97bf78207f
Source dataset
uspto-grants-1984_09
Patent number
US04469636

Reaction notes

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