HuagongsheHuagongshe Chemistry Print Report · For research reference only
Hydroquinone → 4-Methoxyphenol
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Hydroquinone | HCID 785 | — |
| Reactant | Methanol | HCID 887 | — |
| Reactant | Oxygen | HCID 977 | — |
| Catalyst | Iron | HCID 23925 | — |
| Product | 4-Methoxyphenol | HCID 9015 | — |
Reaction Steps
After being filtered, washed with methanol and dried, the resin contains 1.0 milliequivalent of iron per gram of resin. 2.0 g of the catalyst prepared in this manner are fed into the autoclave together with 5.0 g of hydroquinone and 40 cm3 of methanol. The autoclave is pressurised to 5 kg/cm2 with O2 and kept at 105° for 4.5 hours. 4.1 g of hydroquinone monomethyl ether are obtained (conversion 80%, selectivity 91%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04469897 |
| Source dataset | uspto-grants-1984_09 |
| ORD ID | ord-886a606d1e11491da7da887313ad8273 |
| Source note | uspto-grants-1984_09 |