HuagongsheHuagongshe Chemistry Print Report · For research reference only
4-aminophenyl 2,3,6-tri-O-acetyl-4-O-(2,3,4,6-tetra-O-acetyl-alpha-D-glucopyranosyl)-1-thio-beta-D-glucopyranoside → 4-aminophenyl 4-O-(alpha-D-glucopyranosyl)-1-thio-beta-D-glucopyranoside
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 4-aminophenyl 2,3,6-tri-O-acetyl-4-O-(2,3,4,6-tetra-O-acetyl-alpha-D-glucopyranosyl)-1-thio-beta-D-glucopyranoside | HCID 13278993 | — |
| Solvent | Methanol | HCID 887 | — |
| Product | 4-aminophenyl 4-O-(alpha-D-glucopyranosyl)-1-thio-beta-D-glucopyranoside | HCID 54268765 | — |
Reaction Steps
A 3.5 g portion of 4-aminophenyl 2,3,6-tri-O-acetyl-4-O-(2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl)-1-thio-β-D-glucopyranoside was reacted as described in Example 8, giving 1.3 g of the intermediate as a tan solid, [α]D26 =+48°±3° (0.382%, methanol).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04470976 |
| Source dataset | uspto-grants-1984_09 |
| ORD ID | ord-1358437d8ae24a1bbaecd5d700a2b075 |
| Source note | uspto-grants-1984_09 |