HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methyl Bromide → N-{3-[2-Bromo-4-(1,1-dimethylpentyl)-phenyl]-2-methylpropyl}-N-methyl-piperidinium bromide
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methyl Bromide | HCID 6323 | — |
| Reactant | N-{3-[2-Bromo-4-(1,1-dimethylpentyl)-phenyl]-2-methylpropyl}-piperidine | HCID 13142000 | — |
| Solvent | Acetonitrile | HCID 6342 | — |
| Product | N-{3-[2-Bromo-4-(1,1-dimethylpentyl)-phenyl]-2-methylpropyl}-N-methyl-piperidinium bromide | HCID 20446070 | — |
Reaction Steps
17 g of (XIV) in 100 ml of CH3CN were added to a solution of 16.4 g of CH3Br in 200 ml of CH3CN. After 14 hours at room temperature, the mixture was concentrated. The crystalline residue was triturated with ether, filtered off under suction and dried under reduced pressure. Yield: 15 g; melting point: 178° C. (compound No. 78).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04472412 |
| Source dataset | uspto-grants-1984_09 |
| ORD ID | ord-2832c171f0dc4bdcaf3161b98b5c51af |
| Source note | uspto-grants-1984_09 |