HuagongsheHuagongshe Chemistry Print Report · For research reference only
p-Toluenesulfonic acid → 88450-60-6
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | p-Toluenesulfonic acid | HCID 6101 | — |
| Reactant | 2,4-Dichloroaniline | HCID 11123 | — |
| Reactant | 2,4-Dimethylbenzaldehyde | HCID 61814 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | 88450-60-6 | HCID 13339988 | — |
Reaction Steps
A mixture of 26.8 g. of 2,4-dimethylbenzaldehyde, 32.4 g. of 2,4-dichloroaniline, 0.20 g. of p-toluenesulfonic acid, and 150 ml of toluene is stirred under reflux using a Dean-Stark moisture trap. Evaporation of the mixture affords a solid which is recrystallized from ethanol to yield N-(2,4-dimethylbenzylidene)-2,4-dichloroaniline, mp 102°-106°.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04473579 |
| Source dataset | uspto-grants-1984_09 |
| ORD ID | ord-f60acec866b94558b4c5697b721baa83 |
| Source note | uspto-grants-1984_09 |