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HRID2418995

反应详情

EQUATION

反应方程式

HRID 2418995 的结构方程式

REACTANTS

反应物

2
结构：COc1ccccc1N
HCID7000

2-Anisidine

C7H9NO

结构：O=C1c2ccc([N+](=O)[O-])cc2C(=O)c2c1cccc2[N+](=O)[O-]
HCID74147

1,7-Dinitroanthraquinone

C14H6N2O6

PRODUCTS

生成物

1
结构：COc1ccccc1Nc1cccc2c1C(=O)c1cc([N+](=O)[O-])ccc1C2=O
HCID20316485

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

1
结构：COCCO
溶剂HCID8019

2-Methoxyethanol

C3H8O2

PROCEDURE

实验过程

50 g of 1,7-dinitro-anthraquinone and 150 ml of o-anisidine are stirred for 9 hours at 120° - 125° C and then diluted with 150 ml of ethylene glycol monomethyl ether, the mixture is stirred until cold and stirred for several hours longer in an ice bath, and the product is filtered off and successively washed with a little ethylene glycol monomethyl ether, methanol and water. 40.4 g of 1-o-anisidino-7-nitro-anthraquinone are obtained.

WORKUP

后处理

  1. stirringstirred for several hours longer in an ice bath
  2. filtrationthe product is filtered off
  3. washsuccessively washed with a little ethylene glycol monomethyl ether, methanol and water