Methanethiol → 2-Pyrazinyl-ethyl methyl sulfide

HRID 2419200Notes

Reaction equation

HRID 2419200 reaction equation
[CH:1]([C:3]1[CH:8]=[N:7][CH:6]=[CH:5][N:4]=1)=[CH2:2].[CH3:9][SH:10].C(OOC(=O)C1C=CC=CC=1)(=O)C1C=CC=CC=1>>[CH3:9][S:10][CH2:2][CH2:1][C:3]1[CH:8]=[N:7][CH:6]=[CH:5][N:4]=1

Participants

4

Reactant 3

HCID 878MethanethiolHCID 7187Benzoyl PeroxideHCID 77840Vinylpyrazine

Product 1

HCID 226304002-Pyrazinyl-ethyl methyl sulfide

Procedure

h. 2-Pyrazinyl-ethyl methyl sulfide was prepared by reacting vinylpyrazine [c.f. J. Org. Chem. 27, 1363 (1962] with methylmercaptan by the action of ultra violet light and in the presence of benzoyl peroxide by the method described in Acta Chem. Scand. 8,, 295 (1954). The product was identified by mass spectrometry. It has a b.p. of 57°-69° C. at 0.05 mm. Hg.

Sources & evidence

ORD record
ord-7edc151bc3b643169e1c8bbbb262c75d
Source dataset
uspto-grants-1978_08
Patent number
US04105661

Reaction notes

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