Carbon Disulfide → HCID 20315472, compound

HRID 2419321Notes

Reaction equation

[CH3:1][C:2]1[NH:6][CH:5]=[N:4][C:3]=1[CH2:7][S:8]([CH2:10][CH2:11][NH2:12])=[O:9].[C:13](=[S:15])=[S:14]>>[CH3:1][C:2]1[NH:6][CH:5]=[N:4][C:3]=1[CH2:7][S:8]([CH2:10][CH2:11][NH:12][C:13](=[S:14])[SH:15])=[O:9]

Participants

Reactant 2

HCID 6348Carbon Disulfide

HCID 12462377HCID 12462377, compound

Product 1

HCID 20315472HCID 20315472, compound

Procedure

Oxidation of 5-methyl-4-(2-aminoethylthio)methylimidazole with one equivalent of sodium metaperiodate yields 5-methyl-4-(2-aminoethylsulphinyl)methylimidazole and reaction of this compound with carbon disulphide gives N-[2-((5-methyl-4-imidazolyl)methylsulphinyl)ethyl]dithiocarbamic acid which, on treatment with methyl iodide may be converted into S-methyl-N-[2-((5-methyl-4-imidazolyl)methylsulphinyl) ethyl]dithiocarbamate hydriodide.

Sources & evidence

ORD record: ord-080c668c28f74e9da03e2469c174154e
Source dataset: uspto-grants-1978_08
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04105770

Reaction notes

Loading…