29884-24-0 → HCID 19956292, compound

HRID 2419369Notes

Reaction equation

HRID 2419369 reaction equation
[C:1]([C:4]1[CH:18]=[CH:17][C:7]([O:8][C:9]([CH3:16])([CH3:15])[C:10]([O:12][CH2:13][CH3:14])=[O:11])=[CH:6][CH:5]=1)(=[O:3])[CH3:2].[Br:19]CC(C1C=CC(OCC(N2CCOCC2)=O)=CC=1)=O>>[Br:19][CH2:2][C:1]([C:4]1[CH:18]=[CH:17][C:7]([O:8][C:9]([CH3:16])([CH3:15])[C:10]([O:12][CH2:13][CH3:14])=[O:11])=[CH:6][CH:5]=1)=[O:3]

Participants

3

Reactant 2

HCID 1234610829884-24-0HCID 20315597HCID 20315597, compound

Product 1

HCID 19956292HCID 19956292, compound

Procedure

Ethyl 2-[4-acetylphenoxy]-2-methylpropionate was brominated using an analogous procedure to that described for 4-[4-(bromoacetyl)phenoxyacetyl]morpholine, used as a starting material for Example 6, to give ethyl 2-[4-(bromoacetyl)phenoxy]-2-methylpropionate as an oil, which was pure by thin layer chromatographic (TLC) analysis (on silica plates; eluant : 50% ether/50% petrol).

Sources & evidence

ORD record
ord-ffca3cb8853248769876d59fc9a918d2
Source dataset
uspto-grants-1978_08
Patent number
US04105790

Reaction notes

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