HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methyl iodide → 5-Chloro-N-methyl-N-phenyl-1,3-benzodithiol-2-iminium iodide
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methyl iodide | HCID 6328 | — |
| Reactant | 5-Chloro-N-phenyl-1,3-benzodithiol-2-imine | HCID 20313848 | — |
| Solvent | Benzene | HCID 241 | — |
| Product | 5-Chloro-N-methyl-N-phenyl-1,3-benzodithiol-2-iminium iodide | HCID 20313844 | — |
Reaction Steps
A solution of 5-chloro-N-phenyl-1,3-benzodithiol-2-imine (6.0g) and methyl iodide (50 ml, excess) in 200 ml of dry benzene is heated at 50° C for 72 hours. The reaction mixture is filtered and the resultant solid is washed several times with pentane. The solid product is recrystallized from n-amyl alcohol to yield 4.0g of the title compound, melting point 205°-207° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04107175 |
| Source dataset | uspto-grants-1978_08 |
| ORD ID | ord-82509047379048eb8c3b07dc1cf16a13 |
| Source note | uspto-grants-1978_08 |