HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methanol → HCID 54058269, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methanol | HCID 887 | — |
| Reactant | Nitric Acid | HCID 944 | — |
| Reactant | Sodium Hydroxide | HCID 14798 | — |
| Reactant | Nitric acid,thallium(3+) salt, trihydrate (9CI) | HCID 11270721 | — |
| Reactant | HCID 20311359 | HCID 20311359 | — |
| Product | HCID 54058269 | HCID 54058269 | — |
Reaction Steps
Methyl 2-azidomethyl-4-thienyl ketone (9.05 g., 0.05 mole), 150 ml. of methanol, 12.0 g. (0.15 mole) of 70% nitric acid and 22.2 g. (0.05 mole) of thallium (III) nitrate trihydrate is heated at reflux for 2 hours, cooled to room temperature, neutralized with dilute sodium hydroxide solution, filtered and the filtrate worked-up as described in Example 4 to obtain the title compound.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04110342 |
| Source dataset | uspto-grants-1978_08 |
| ORD ID | ord-0b4014637e554185b96b4b791147fb20 |
| Source note | uspto-grants-1978_08 |