3,4-Dichloroaniline → HCID 19006421, compound

HRID 2420464Notes

Reaction equation

HRID 2420464 reaction equation
[Cl:1][C:2]1[CH:14]=[CH:13][CH:12]=[C:11]([Cl:15])[C:3]=1[C:4]([NH:6][C:7](=[S:10])[SH-]C)=[S:5].[Cl:16][C:17]1[CH:18]=[C:19]([CH:21]=[CH:22][C:23]=1[Cl:24])[NH2:20]>C1(C)C=CC=CC=1>[Cl:15][C:11]1[CH:12]=[CH:13][CH:14]=[C:2]([Cl:1])[C:3]=1[C:4]([NH:6][C:7]([NH:20][C:19]1[CH:21]=[CH:22][C:23]([Cl:24])=[C:17]([Cl:16])[CH:18]=1)=[S:10])=[S:5]

Participants

4

Reactant 2

HCID 72573,4-DichloroanilineHCID 178504154HCID 178504154, compound

Product 1

HCID 19006421HCID 19006421, compound

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Procedure

3.0 g of N-(2,6-dichlorothiobenzoyl)-S-methyl-dithiocarbamate and 1.6 g of 3,4-dichloroaniline are dissolved in 25 ml of toluene and subsequently heated while refluxing for 5 hours. The resulting yellow precipitate is worked up in the usual manner. Yield 2.1 g. Melting point 168°-170° C.

Workup

  1. temperaturesubsequently heated
  2. temperaturewhile refluxing for 5 hours

Sources & evidence

ORD record
ord-171055c28d3240a4a4a6921c59c5d922
Source dataset
uspto-grants-1978_08
Patent number
US04110469

Reaction notes

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