Isopropyltriphenylphosphonium iodide → Methyl 2'-isobutyl-6'-methylbiphenyl-3-carboxylate

HRID 2422274Notes

Reaction equation

HRID 2422274 reaction equation
[CH:1]([C:3]1[CH:8]=[CH:7][CH:6]=[C:5]([CH3:9])[C:4]=1[C:10]1[CH:15]=[CH:14][CH:13]=[C:12]([C:16]([O:18][CH3:19])=[O:17])[CH:11]=1)=O.[I-].[CH:21]([P+](C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1)([CH3:23])[CH3:22]>>[CH2:1]([C:3]1[CH:8]=[CH:7][CH:6]=[C:5]([CH3:9])[C:4]=1[C:10]1[CH:15]=[CH:14][CH:13]=[C:12]([C:16]([O:18][CH3:19])=[O:17])[CH:11]=1)[CH:21]([CH3:23])[CH3:22]

Participants

3

Reactant 2

HCID 2723783Isopropyltriphenylphosphonium iodideHCID 23083093Methyl 2'-formyl-6'-methylbiphenyl-3-carboxylate

Product 1

HCID 23083073Methyl 2'-isobutyl-6'-methylbiphenyl-3-carboxylate

Procedure

The title compound was synthesized in the same manner as in Reference Example 217 from methyl 2′-formyl-6′-methylbiphenyl-3-carboxylate and isopropyltriphenylphosphonium iodide. colorless oil (yield 45%).

Sources & evidence

ORD record
ord-ff40c6cc04594284bbfd9569d2d19dcf
Source dataset
uspto-grants-2011_06
Patent number
US07960369B2

Reaction notes

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