Potassium Nitrate → HCID 59745249, compound

HRID 2422832Notes

Reaction equation

HRID 2422832 reaction equation
[CH2:1]([O:3][C:4](=[O:16])[NH:5][C:6]1[CH:7]=[C:8]2[C:12](=[CH:13][CH:14]=1)[C:11](=[O:15])[CH2:10][CH2:9]2)[CH3:2].[N+:17]([O-])([O-:19])=[O:18].[K+]>S(=O)(=O)(O)O>[CH2:1]([O:3][C:4](=[O:16])[NH:5][C:6]1[C:7]([N+:17]([O-:19])=[O:18])=[C:8]2[C:12](=[CH:13][CH:14]=1)[C:11](=[O:15])[CH2:10][CH2:9]2)[CH3:2]

Participants

4

Reactant 2

HCID 24434Potassium NitrateHCID 20231968HCID 20231968, compound

Product 1

HCID 59745249HCID 59745249, compound

Reagents, catalysts & solvents 1

HCID 1118Sulfuric AcidSolvent

Conditions

Temperature
0 °C

Procedure

(1-Oxo-indan-5-yl)-carbamic acid ethyl ester (0.94 g, 4.3 mmol) was dissolved in 20 ml of concentrated sulphuric acid and cooled to 0° C. using an ice-bath. Potassium nitrate (477 mg, 4.7 mmol) was added in small portions. After complete addition, the mixture was stirred for 3 hours at 0° C. and then poured onto crushed ice. The yellow precipitate was filtered off, washed thoroughly with water and dried in vacuo to give a yellow solid product (0.85, 75%).

Workup

  1. additionAfter complete addition
  2. additionpoured
  3. customonto crushed ice
  4. filtrationThe yellow precipitate was filtered off
  5. washwashed thoroughly with water
  6. customdried in vacuo
  7. customto give a yellow solid product (0.85, 75%)

Sources & evidence

ORD record
ord-7d13cc696043442287f7f6dcda2341fe
Source dataset
uspto-grants-2011_06
Patent number
US07960436B2

Reaction notes

Loading…