HuagongsheHuagongshe Chemistry Print Report · For research reference only
Sodium Sulfite → HCID 51072214, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Sodium Sulfite | HCID 24437 | — |
| Reactant | m-Chloroperbenzoic acid | HCID 70297 | — |
| Reactant | Thiane-4-carbonitrile | HCID 21598641 | — |
| Solvent | Chloroform | HCID 6212 | — |
| Product | HCID 51072214 | HCID 51072214 | — |
Reaction Steps
A chloroform solution of tetrahydro-2H-thiopyran-4-carbonitrile was dropwise added to a chloroform solution of 77% m-chloroperbenzoic acid at 0° C., followed by stirring at room temperature for 3 hours. An excess amount of an aqueous saturated sodium sulfite solution was added, followed by work-up to obtain tetrahydro-2H-thiopyran-4-carbonitrile 1,1-dioxide.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07960562B2 |
| Source dataset | uspto-grants-2011_06 |
| ORD ID | ord-7520cfbeca63418ea09869d05de4f736 |
| Source note | uspto-grants-2011_06 |