5-Bromopyridine-3-sulfonyl chloride → HCID 59532409, compound

Participants

Reaction Steps

The title compound was prepared from D7 and 3-bromopyridine-5-sulfonyl chloride using a method similar to that described for D15 except that the reaction time was overnight and column chromatography was carried out eluting with 0-100% Et2O/petroleum ether. δH (CDCl3, 400 MHz) 8.83 (1H, d), 8.80 (1H, d), 8.12 (1H, t), 7.16 (1H, d), 7.13 (1H, br.s), 6.92 (1H, d), 6.86 (1H, dd), 4.17 (1H, br.s), 3.77 (1H, d), 3.34 (2H, s), 2.99 (1H, m), 2.64 (1H, m), 2.51 (1H, d), 2.31 (3H, s), 2.14 (1H, m), 1.96 (1H, m), 1.46 (9H, s), 1.17 (3H, d). MS (ES+): MH+ 539/541.

Provenance & Evidence