HuagongsheHuagongshe Chemistry Print Report · For research reference only
4-(Methylthio)phenylboronic acid → [1,1'-Biphenyl]-4-sulfonamide, N-(4-hydroxybutyl)-4'-(methylthio)-
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 4-(Methylthio)phenylboronic acid | HCID 2733959 | — |
| Reactant | 4-Bromo-N-(4-hydroxybutyl)benzene-1-sulfonamide | HCID 16094720 | — |
| Product | [1,1'-Biphenyl]-4-sulfonamide, N-(4-hydroxybutyl)-4'-(methylthio)- | HCID 11609999 | — |
Reaction Steps
Using a method analogous to that described in Example 40, 4-bromophenyl-sulfonic acid-(4-hydroxybutyl)-amide and 4-methylthiophenyl boronic acid were reacted to give the title compound as a white solid. δC (DMSO, 62.9 MHz): 14.5, 25.9, 29.6, 42.6, 60.2, 125.9 126.2, 127.1, 127.3, 127.5, 134.8, 139.1 and 143.1.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07964643B2 |
| Source dataset | uspto-grants-2011_06 |
| ORD ID | ord-81c5e361ad1d401980cfb89a191362af |
| Source note | uspto-grants-2011_06 |