HRID2425819

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID180

Acetone

C3H6O

HCID10666287

未命名化合物

HCID59538313

未命名化合物

PRODUCTS

生成物

结构：O=C(CCC[n+]1ccc(N=Nc2ccc(N(CCO)CCO)cc2)c2ccccc21)NCCSSCCNC(=O)CCC[n+]1ccc(N=Nc2ccc(N(CCO)CCO)cc2)c2ccccc21.[Cl-].[Cl-]

HCID86646634

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID6342

Acetonitrile

C2H3N

PROCEDURE

实验过程

0.35 g of 2,2′-({4-[(quinolin-4-yl)diazenyl]-phenyl}-imino)diethanol and 0.18 g of N,N′-(disulfanediyldiethane-2,1-diyl)bis(4-chlorobutanamide) are solubilized in 2 mL acetonitrile. The mixtured is heated at reflux for 24 h, cooled and poured on 50 mL acetone. The resulting oil is washed several times with acetone.

WORKUP

后处理

temperatureThe mixtured is heated
temperatureat reflux for 24 h
temperaturecooled
washThe resulting oil is washed several times with acetone

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-44b681326fc849a398eee097b64a9b42
来源数据集: uspto-grants-2011_06
DOI: 10.6084/m9.figshare.5104873.v1
专利: US07967872B2
来源说明: uspto-grants-2011_06

反应 SMILES

[N:1]1[C:10]2[C:5](=[CH:6][CH:7]=[CH:8][CH:9]=2)[C:4]([N:11]=[N:12][C:13]2[CH:18]=[CH:17][C:16]([N:19]([CH2:23][CH2:24][OH:25])[CH2:20][CH2:21][OH:22])=[CH:15][CH:14]=2)=[CH:3][CH:2]=1.[S:26]([CH2:37][CH2:38][NH:39][C:40](=[O:45])[CH2:41][CH2:42][CH2:43]Cl)[S:27][CH2:28][CH2:29][NH:30][C:31](=[O:36])[CH2:32][CH2:33][CH2:34][Cl:35].C[C:47]([CH3:49])=[O:48]>C(#N)C>[Cl-:35].[Cl-:35].[S:26]([CH2:37][CH2:38][NH:39][C:40](=[O:45])[CH2:41][CH2:42][CH2:43][N+:1]1[C:10]2[C:5](=[CH:6][CH:7]=[CH:8][CH:9]=2)[C:4]([N:11]=[N:12][C:13]2[CH:18]=[CH:17][C:16]([N:19]([CH2:49][CH2:47][OH:48])[CH2:20][CH2:21][OH:22])=[CH:15][CH:14]=2)=[CH:3][CH:2]=1)[S:27][CH2:28][CH2:29][NH:30][C:31](=[O:36])[CH2:32][CH2:33][CH2:34][N+:1]1[C:10]2[C:5](=[CH:6][CH:7]=[CH:8][CH:9]=2)[C:4]([N:11]=[N:12][C:13]2[CH:14]=[CH:15][C:16]([N:19]([CH2:23][CH2:24][OH:25])[CH2:20][CH2:21][OH:22])=[CH:17][CH:18]=2)=[CH:3][CH:2]=1