HuagongsheHuagongshe Chemistry Print Report · For research reference only
Imidazole → 4'-{[Tert-butyl(dimethyl)silyl]oxy}-2',6'-dimethylbiphenyl-3-carbaldehyde
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Imidazole | HCID 795 | — |
| Reactant | tert-Butyldimethylsilyl chloride | HCID 28928 | — |
| Reactant | 4'-Hydroxy-2',6'-dimethyl-[1,1'-biphenyl]-3-carbaldehyde | HCID 23111691 | — |
| Solvent | Dimethylformamide | HCID 6228 | — |
| Product | 4'-{[Tert-butyl(dimethyl)silyl]oxy}-2',6'-dimethylbiphenyl-3-carbaldehyde | HCID 59838330 | — |
Reaction Steps
By adding tert-butyl(dimethyl)silyl chloride to a DMF solution of 4′-hydroxy-2′,6′-dimethylbiphenyl-3-carbaldehyde and imidazole, and stirring at room temperature for 10 hours, 4′-{[tert-butyl(dimethyl)silyl]oxy}-2′,6′-dimethylbiphenyl-3-carbaldehyde was obtained.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07968552B2 |
| Source dataset | uspto-grants-2011_06 |
| ORD ID | ord-628144aa33554a3f89e5799d32a9ea38 |
| Source note | uspto-grants-2011_06 |