HCID 67252107, compound → HCID 57787581, compound

HRID 2426767Notes

Reaction equation

HRID 2426767 reaction equation
[OH:1][CH2:2][C:3]1[CH:30]=[CH:29][C:6]([O:7][CH2:8][C:9]2[CH:10]=[C:11]([C:15]3[C:20]([CH3:21])=[CH:19][C:18]([O:22][CH2:23][C:24]([CH3:27])([OH:26])[CH3:25])=[CH:17][C:16]=3[CH3:28])[CH:12]=[CH:13][CH:14]=2)=[CH:5][CH:4]=1>[O-2].[O-2].[Mn+4].C(Cl)(Cl)Cl>[OH:26][C:24]([CH3:27])([CH3:25])[CH2:23][O:22][C:18]1[CH:17]=[C:16]([CH3:28])[C:15]([C:11]2[CH:12]=[CH:13][CH:14]=[C:9]([CH2:8][O:7][C:6]3[CH:5]=[CH:4][C:3]([CH:2]=[O:1])=[CH:30][CH:29]=3)[CH:10]=2)=[C:20]([CH3:21])[CH:19]=1

Participants

4

Reactant 1

HCID 67252107HCID 67252107, compound

Product 1

HCID 57787581HCID 57787581, compound

Reagents, catalysts & solvents 2

HCID 178418406HCID 178418406, compoundCatalystHCID 6212ChloroformSolvent

Conditions

Temperature
50 °C

Procedure

A mixture of 1-[(3′-{[4-(hydroxymethyl)phenoxy]methyl}-2,6-dimethylbiphenyl-4-yl)oxy]-2-methylpropan-2-ol, manganese dioxide and chloroform was stirred with heating at 50° C. for 20 hours to obtain 4-{[4′-(2-hydroxy-2-methylpropoxy)-2′,6′-dimethylbiphenyl-3-yl]methoxy}benzaldehyde.

Sources & evidence

ORD record
ord-9a10d18332914952943e26391057df34
Source dataset
uspto-grants-2011_06
Patent number
US07968552B2

Reaction notes

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