HuagongsheHuagongshe Chemistry Print Report · For research reference only
Ceric ammonium nitrate → 2-Hydroxy-n-isobutyl-2-methyl-4-(2,4,5-trimethyl-3,6-dioxocyclohexa-1,4-dienyl)butanamide
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Ceric ammonium nitrate | HCID 180504 | — |
| Reactant | 6-hydroxy-N-isobutyl-2,5,7,8-tetramethylchroman-2-carboxamide | HCID 67263059 | — |
| Product | 2-Hydroxy-n-isobutyl-2-methyl-4-(2,4,5-trimethyl-3,6-dioxocyclohexa-1,4-dienyl)butanamide | HCID 42599126 | 87.3% |
Reaction Steps
Oxidation as described in protocol B, using 84 mg (0.278 mmol) of 6-hydroxy-N-isobutyl-2,5,7,8-tetramethylchroman-2-carboxamide and 335 mg CAN (0.612 mmol) yielded 78 mg of 2-hydroxy-N-isobutyl-2-methyl-4-(2,4,5-trimethyl-3,6-dioxocyclohexa-1,4-dienyl)butanamide as a yellow-orange oil.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07968746B2 |
| Source dataset | uspto-grants-2011_06 |
| ORD ID | ord-1c7781ff41594168a744231ffaec65df |
| Source note | uspto-grants-2011_06 |