HuagongsheHuagongshe Chemistry Print Report · For research reference only
Phosphorus pentachloride → 3-Chloro-2-cyclohexyl-5-methoxy-2H-1,2,4,6-thiatriazine-1,1-dioxide
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Phosphorus pentachloride | HCID 24819 | — |
| Reactant | 2-Cyclohexyl-5-methoxy-2H-1,2,4,6-thiatriazin-3-one-1,1-dioxide | HCID 13017764 | — |
| Solvent | Phosphorus oxychloride | HCID 24813 | — |
| Product | 3-Chloro-2-cyclohexyl-5-methoxy-2H-1,2,4,6-thiatriazine-1,1-dioxide | HCID 12917985 | — |
Reaction Steps
A mixture of the thiatriazinone from Step 2. above (77.3 g) and phosphorus pentachloride (92.4 g) in phosphorus oxychloride (230 ml) is refluxed overnight. The reaction mixture is evaporated at 50° C. yielding an oil (92.3 g) which is used without further purification in the next step.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04704388 |
| Source dataset | uspto-grants-1987_11 |
| ORD ID | ord-7ab42ecd3ff546969806cdbe676df467 |
| Source note | uspto-grants-1987_11 |