HuagongsheHuagongshe Chemistry Print Report · For research reference only
Ethanol → HCID 70431325, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Ethanol | HCID 702 | — |
| Reactant | Methylamine | HCID 6329 | — |
| Reactant | 3-(3,4-Dichlorophenyl)bicyclo[2.2.2]oct-2-ene-2-carbaldehyde | HCID 20161611 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | HCID 70431325 | HCID 70431325 | — |
Reaction Steps
A 33% solution of methylamine in ethanol (250 ml) was added in one lot to 3-formyl-2-(3,4-dichlorophenyl)bicyclo[2,2,2]oct-2-ene (25 g; 0.089 m) in dichloromethane (50 ml) at 0° C. After 1 hour, the solution was evaporated to yield an oil. Yield 26 g. (100%). An infrared spectrum showed complete loss of the carbonyl group. A peak at 1630 cm-1 indicated the presence of an imine (--CH=N--Me group). M+ 293/295.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04705807 |
| Source dataset | uspto-grants-1987_11 |
| ORD ID | ord-8db462e7dd2e436e82a6d961f0b36004 |
| Source note | uspto-grants-1987_11 |