Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Chlorine | HCID 24526 | — |
| Reactant | 2-{Bis(2-fluoro-2,2-dinitroethoxy)[(trichloromethyl)disulfanyl]methoxy}-1-fluoro-1,1-dinitroethane | HCID 13149208 | — |
| Reactant | 3,3'-[Methylenebis(oxy)]bis(2,2-dinitropropan-1-ol) | HCID 15807500 | — |
| Solvent | 1,2-Dichloroethane | HCID 11 | — |
| Product | HCID 20162005 | HCID 20162005 | — |
Reaction Steps
Chlorine gas was passed into a solution of 3.78 g (0.011 mol) of 2,2,8,8-tetranitro-4,6-dioxanonane-1,9-diol and 6.53 g (0.01 mol) of tris(2-fluoro-2,2-dinitroethoxy)methyl trichloromethyl disulfide in 20 ml of dry 1,2-dichloroethane at 65° C. for two hours. Heating at 65° C. was continued for 22 hours at which time the solvent was removed and the oily residue was washed with 2×30 ml of hexane. Thin layer chromatography indicated the product was a mixture of the mono-(XI) and the bis-orthocarbonate (XII). The mono-orthocarbonate (XI) was isolated by column chromatography (silica gel 60, methylene chloride-ethyl acetate (90:10) as eluent) as a viscous gummy oil; H-NMR [(CD3)2C=O]: δ 5.20 (d), 4.96 (s), 4.83 (s), 4.68 (s), 4.58 (s), 4.54 (s). IR (film on NaCl plate) 3600 (OH), 1600 (NO2) cm-1.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US04705899 |
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| Source dataset | uspto-grants-1987_11 |
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| ORD ID | ord-8ac92bd2d6c940b186f69659c9aad246 |
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| Source note | uspto-grants-1987_11 |
|---|
