Sodium Azide → HCID 178493643, compound

HRID 247425Notes

Reaction equation

HRID 247425 reaction equation
[F:1][C:2]1[CH:3]=[C:4]([CH2:11][CH2:12][CH2:13][N:14]=[C:15]=[S:16])[CH:5]=[C:6]([F:10])[C:7]=1[O:8][CH3:9].[N-:17]=[N+:18]=[N-:19].[Na+]>>[F:1][C:2]1[CH:3]=[C:4]([CH2:11][CH2:12][CH2:13][N:14]2[C:15]([SH:16])=[N:19][N:18]=[N:17]2)[CH:5]=[C:6]([F:10])[C:7]=1[O:8][CH3:9]

Participants

3

Reactant 2

HCID 33557Sodium AzideHCID 14581314HCID 14581314, compound

Product 1

HCID 178493643HCID 178493643, compoundYield 39%

Procedure

3-(3,5-Difluoro-4-methoxyphenyl)propylisothiocyanate (0.036 mol) and sodium azide (0.054 mol) were reacted substantially as described in Example 7H above to give 4 g (39%) white crystals: mp 64°-65°.

Sources & evidence

ORD record
ord-5ea2320dcaf14afd85cd2be317559028
Source dataset
uspto-grants-1987_11
Patent number
US04707488

Reaction notes

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