HCID 14028949, compound → HCID 14028950, compound

HRID 247566Notes

Reaction equation

HRID 247566 reaction equation
[N+:1]([C:4]1[CH:9]=[CH:8][C:7]([S:10][C:11]2[CH:16]=[CH:15][C:14]([C:17]([C:26]3[CH:31]=[CH:30][C:29]([S:32][C:33]4[CH:38]=[CH:37][C:36]([N+:39]([O-])=O)=[CH:35][CH:34]=4)=[CH:28][CH:27]=3)([C:22]([F:25])([F:24])[F:23])[C:18]([F:21])([F:20])[F:19])=[CH:13][CH:12]=2)=[CH:6][CH:5]=1)([O-])=O.[H][H]>[Pd].C(O)C>[NH2:39][C:36]1[CH:35]=[CH:34][C:33]([S:32][C:29]2[CH:30]=[CH:31][C:26]([C:17]([C:14]3[CH:15]=[CH:16][C:11]([S:10][C:7]4[CH:6]=[CH:5][C:4]([NH2:1])=[CH:9][CH:8]=4)=[CH:12][CH:13]=3)([C:18]([F:21])([F:19])[F:20])[C:22]([F:23])([F:24])[F:25])=[CH:27][CH:28]=2)=[CH:38][CH:37]=1

Participants

5

Reactant 2

HCID 14028949HCID 14028949, compound2×HCID 178418361HCID 178418361, compound

Product 1

HCID 14028950HCID 14028950, compound

Reagents, catalysts & solvents 2

HCID 23938PalladiumCatalystHCID 702EthanolSolvent

Procedure

Compound 8 was is prepared by hydrogenating 2,2-bis[4-(4-nitrophenylthio)phenyl]hexafluoropropane (Compound 7) in a Parr apparatus under 4 atmospheres of hydrogen over palladium-on-charcoal catalyst in ethyl alcohol solvent.

Sources & evidence

ORD record
ord-b0285d9813b646b0ad2ff752e9b4895e
Source dataset
uspto-grants-1987_11
Patent number
US04708991

Reaction notes

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