Aluminum isopropoxide → HCID 86745678, compound

HRID 247806Notes

Reaction equation

[CH3:1][CH:2]([CH3:4])[O-:3].[Al+3:5].[CH3:6][CH:7]([CH3:9])[O-:8].[CH3:10][CH:11]([CH3:13])[O-:12].[O-]CC.[Mg+2:17].[O-]CC>>[O-:3][CH2:2][CH3:1].[Mg+2:17].[O-:8][CH2:7][CH3:6].[CH3:10][CH:11]([CH3:13])[O-:12].[Al+3:5].[CH3:1][CH:2]([CH3:4])[O-:3].[CH3:6][CH:7]([CH3:9])[O-:8]

Participants

Reactant 2

HCID 11143Aluminum isopropoxide

HCID 164963Magnesium ethanolate

Product 1

HCID 86745678HCID 86745678, compound

Procedure

One gram (5 mmoles) of aluminum isopropoxide was dissolved in 10 ml of Freon TF solvent and 0.7 grams (6 mmoles) of magnesium ethoxide added. After mixing in an ultra-sonic bath, followed by settling of suspended matter, 3 ml of the clear solution was analyzed for Mg and Al. Theory Al: 1.5 mmole, Found Al: 1.5 mmole. Theory Mg: 1.8 mmoles, Found Mg: 0.08 mmoles. Conclusion: Little effect of Aluminum alkoxide on solubility of Magnesium alkoxide in Freon TF, and therefore not a useful system for deacidification of books.

Workup

additionadded
additionAfter mixing in an ultra-sonic bath

Sources & evidence

ORD record: ord-2997b9b30bf3498596212c7b6d57a357
Source dataset: uspto-grants-1993_05
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05208072

Reaction notes

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