1-Dodecanol → HCID 57935340, compound

HRID 247824Notes

Reaction equation

[CH3:1][CH:2]([C:4]1[CH:9]=[CH:8][CH:7]=[C:6]([CH:10]([CH3:12])[CH3:11])[C:5]=1[NH:13][C:14](=[O:25])[CH2:15][P:16]([C:19]1[CH:24]=[CH:23][CH:22]=[CH:21][CH:20]=1)(=[O:18])[OH:17])[CH3:3].[CH2:26](O)[CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH3:37]>>[CH3:12][CH:10]([C:6]1[CH:7]=[CH:8][CH:9]=[C:4]([CH:2]([CH3:1])[CH3:3])[C:5]=1[NH:13][C:14](=[O:25])[CH2:15][P:16]([C:19]1[CH:24]=[CH:23][CH:22]=[CH:21][CH:20]=1)(=[O:17])[O:18][CH2:37][CH2:36][CH2:35][CH2:34][CH2:33][CH2:32][CH2:31][CH2:30][CH2:29][CH2:28][CH2:27][CH3:26])[CH3:11]

Participants

Reactant 2

HCID 81931-Dodecanol

HCID 19764426HCID 19764426, compound

Product 1

HCID 57935340HCID 57935340, compound

Procedure

In a process analogous to Example 7, using (±)-[2-[[2,6-bis(1-methylethyl)phenyl]amino]-2-oxoethyl]phenyl phosphinic acid in place of (±)-[2-[[2,6-bis(1-methylethyl)phenyl]amino]-2-oxoethyl]phosphonic acid, ethyl ester and 1-dodecanol in place of 1-nonanol, the title compound is obtained as a sticky white solid; mp 66°-68° C.

Sources & evidence

ORD record: ord-582a8a39dcd348d195f6f383bef92f05
Source dataset: uspto-grants-1993_05
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05208224

Reaction notes

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