Methyl iodide → HCID 10100640, compound

HRID 247959Notes

Reaction equation

[C:1]([N:4]([CH2:30][C:31]1[CH:36]=[CH:35][CH:34]=[CH:33][N:32]=1)[C:5](=[O:29])[C:6]1[CH:11]=[CH:10][C:9]([O:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH3:26])=[C:8]([O:27][CH3:28])[CH:7]=1)(=[O:3])[CH3:2].[CH3:37][I:38]>>[I-:38].[C:1]([N:4]([CH2:30][C:31]1[CH:36]=[CH:35][CH:34]=[CH:33][N+:32]=1[CH3:37])[C:5](=[O:29])[C:6]1[CH:11]=[CH:10][C:9]([O:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH3:26])=[C:8]([O:27][CH3:28])[CH:7]=1)(=[O:3])[CH3:2]

Participants

Reactant 2

HCID 6328Methyl iodide

HCID 10097364HCID 10097364, compound

Product 1

HCID 10100640HCID 10100640, compoundYield 99.3%

Procedure

The title compound is prepared by the procedure of Example 28 using 0.322 g of product from Example 49 and 4.6 g of methyl iodide. The residue is recrystallized from methyl alcohol to give 0.411 g of the desired product as yellow crystals.

Workup

customThe residue is recrystallized from methyl alcohol

Sources & evidence

ORD record: ord-e22bf4d43c6e474c877cf53c13f6d48f
Source dataset: uspto-grants-1993_05
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05208247

Reaction notes

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