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HRID248621

反应详情

EQUATION

反应方程式

HRID 248621 反应方程式

REACTANTS

反应物

3
Benzoyl peroxide 分子结构式
HCID7187

Benzoyl peroxide

C14H10O4

1-Bromopyrrolidine-2,5-dione 分子结构式
HCID67184

1-Bromopyrrolidine-2,5-dione

C4H4BrNO2

5-(4'-Methyl[1,1'-biphenyl]-2-yl)-1-(triphenylmethyl)-1H-tetrazole 分子结构式
HCID10152019

5-(4'-Methyl[1,1'-biphenyl]-2-yl)-1-(triphenylmethyl)-1H-tetrazole

C33H26N4

PRODUCTS

产物

1
5-[4'-(Bromomethyl)[1,1'-biphenyl]-2-yl]-1-(triphenylmethyl)-1H-tetrazole 分子结构式
HCID10053461

5-[4'-(Bromomethyl)[1,1'-biphenyl]-2-yl]-1-(triphenylmethyl)-1H-tetrazole

C33H25BrN4

AUXILIARIES

试剂、催化剂与溶剂

1
Carbon tetrachloride 分子结构式
溶剂HCID5943

Carbon tetrachloride

CCl4

PROCEDURE

实验过程

A mixture of N-triphenylmethyl 5-(4'-methylbiphenyl-2-yl)tetrazole (Example 11, 12.7 g), N-bromosuccinimide (4.6 g), carbon tetrachloride (300 mL), and benzoyl peroxide (75 mg) was heated at reflux for 2.5 hours. The cooled suspension was filtered and the filtrate was evaporated to give the title compound as a crystalline solid. 1H-NMR (CDCl3) δ 8.2 6.7 (complex, 23H), 4.3 (s, 2H).

WORKUP

后处理

  1. temperaturewas heated
  2. temperatureat reflux for 2.5 hours
  3. filtrationThe cooled suspension was filtered
  4. customthe filtrate was evaporated