HuagongsheHuagongshe Chemistry Print Report · For research reference only
Diethyl Carbonate → Diethylene glycol diethyl ether
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Diethyl Carbonate | HCID 7766 | — |
| Reactant | Diethylene Glycol Monoethyl Ether | HCID 8146 | — |
| Reactant | Aluminum | HCID 5359268 | — |
| Reactant | Magnesium | HCID 5462224 | — |
| Product | Diethylene glycol diethyl ether | HCID 8179 | — |
Reaction Steps
A mixture of 2-(2-ethoxyethoxy)ethanol (1 mole) and diethyl carbonate (3 mole) was passed through 11.5 grams of a magnesium:aluminum mixed metal oxide (3/16 inch pellets, Mg/Al 3:1) at a temperature of 225° C. and at a liquid feed rate of 0.29 milliliters/minute. After a period of one hour, a total of 30.2 grams of liquid was collected. Analysis was performed by capillary gas chromatography (FID) using a DB-1701 column. The results were (area %) as follows:
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05210322 |
| Source dataset | uspto-grants-1993_05 |
| ORD ID | ord-528009b6826c405d946c3525eea95ba5 |
| Source note | uspto-grants-1993_05 |