HuagongsheHuagongshe Chemistry Print Report · For research reference only
1-Decanol → Decane, 1-methoxy-
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1-Decanol | HCID 8174 | — |
| Reactant | Dimethyl Carbonate | HCID 12021 | — |
| Reactant | Aluminum | HCID 5359268 | — |
| Reactant | Magnesium | HCID 5462224 | — |
| Product | Decane, 1-methoxy- | HCID 23716 | — |
Reaction Steps
A mixture of 1-decanol (1 mole) and dimethyl carbonate (3 mole) was passed through 11.5 grams of a magnesium:aluminum mixed metal oxide (3/16 inch pellets, Mg/Al 3:1) at a temperature of 250° C. and at a liquid feed rate of 0.34 milliliters/minute. After a period of 1.1 hour, a total of 36.5 grams of liquid was collected. Analysis was performed by capillary gas chromatography (FID) using a DB-1701 column. The results were (area %) as follows:
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05210322 |
| Source dataset | uspto-grants-1993_05 |
| ORD ID | ord-432ef82c4ca247998bca2792643cc0dc |
| Source note | uspto-grants-1993_05 |