HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methyl Acrylate → Methyl 3-[(2-thienylmethyl)thio]propanoate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methyl Acrylate | HCID 7294 | — |
| Reactant | Piperidine | HCID 8082 | — |
| Reactant | Benzyltrimethylammonium hydroxide | HCID 66854 | — |
| Reactant | Thenyl mercaptan | HCID 80408 | — |
| Product | Methyl 3-[(2-thienylmethyl)thio]propanoate | HCID 15225387 | — |
Reaction Steps
A solution of 2-thiophenemethanethiol (12 grams), methylacrylate (7.94 grams), piperidine (3 mL) and N-benzyltrimethylammonium hydroxide (3 mL) was stirred for 16 hours at room temperature. The reaction mixture was distilled in vacuo to yield the desired title compound. Yield: 16.5 grams (83%). Bp: 140° C. at 1 mmHg.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05212169 |
| Source dataset | uspto-grants-1993_05 |
| ORD ID | ord-9c6e7bf39f6f4949ae051db4b2cfae12 |
| Source note | uspto-grants-1993_05 |