Ammonia → HCID 13650746, compound

HRID 248859Notes

Reaction equation

HRID 248859 reaction equation
[CH3:1][CH:2]([CH:5]([C:9]1[CH:14]=[CH:13][C:12]([C:15]([CH3:18])([CH3:17])[CH3:16])=[CH:11][CH:10]=1)[CH2:6][CH:7]=O)[CH:3]=O.[NH3:19].[H][H]>>[C:15]([C:12]1[CH:13]=[CH:14][C:9]([CH:5]2[CH2:6][CH2:7][NH:19][CH2:3][CH:2]2[CH3:1])=[CH:10][CH:11]=1)([CH3:18])([CH3:17])[CH3:16]

Participants

4

Reactant 3

HCID 222AmmoniaHCID 57173935HCID 57173935, compoundHCID 178418361HCID 178418361, compound

Product 1

HCID 13650746HCID 13650746, compound

Procedure

2-Methyl-3-(p-tert.-butylphenyl)-1,5-pentanedial (VI) can be hydrogenated with ammonia and hydrogen in the presence of a hydrogenation catalyst to give 4-(p-tert.-butylphenyl)-3-methylpiperidine (VII). ##STR8##

Sources & evidence

ORD record
ord-501ebe99c0004174a0f45f098477dfba
Source dataset
uspto-grants-1993_05
Patent number
US05212183

Reaction notes

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