Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Phenacylamine → 2-Aminoacetophenone 4-chlorophenylhydrazone
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Phenacylamine | HCID 11952 | — |
| 반응물 | (4-Chlorophenyl)hydrazine | HCID 70624 | — |
| 용매 | Acetic Acid | HCID 176 | — |
| 용매 | Ethanol | HCID 702 | — |
| 용매 | Water | HCID 962 | — |
| 생성물 | 2-Aminoacetophenone 4-chlorophenylhydrazone | HCID 86746351 | 84% |
반응 단계
A mixture of 10.43 g 2-aminoacetophenone and 11.0 g 4-chlorophenylhydrazine in 30 ml EtOH and 10 ml HOAc was refluxed for one hour. The cooled reaction mixture was diluted with water and the precipitate was collected, washed with water, and dried to give 16.83 g solid. Recrystallization from methanol gave 3.48 g solid, m.p. 109°-112° C.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05214059 |
| 출처 데이터셋 | uspto-grants-1993_05 |
| ORD ID | ord-fd729e02bed74f7e97efb42406945fc6 |
| 출처 메모 | uspto-grants-1993_05 |