Stannous Chloride → 4-[3-(Dimethylamino)-1-propyn-1-yl]benzenamine

HRID 24934Notes

Reaction equation

HRID 24934 reaction equation
[CH3:1][N:2]([CH3:15])[CH2:3][C:4]#[C:5][C:6]1[CH:11]=[CH:10][C:9]([N+:12]([O-])=O)=[CH:8][CH:7]=1.[Sn](Cl)Cl>>[CH3:15][N:2]([CH3:1])[CH2:3][C:4]#[C:5][C:6]1[CH:7]=[CH:8][C:9]([NH2:12])=[CH:10][CH:11]=1

Participants

3

Reactant 2

HCID 24479Stannous ChlorideHCID 22569284N,N-Dimethyl-3-(4-nitrophenyl)prop-2-yn-1-amine

Product 1

HCID 225697414-[3-(Dimethylamino)-1-propyn-1-yl]benzenamine

Procedure

The reaction of 4-(3-dimethylaminoprop-1-ynyl)-nitrobenzene with tin dichloride analogously to Example 269 yields the following three products:

Workup

  1. customyields the following three products

Sources & evidence

ORD record
ord-067d6bec0fdf4bb58506b1bbddd23e91
Source dataset
uspto-grants-2005_02
Patent number
US06855710B2

Reaction notes

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