HuagongsheHuagongshe Chemistry Print Report · For research reference only
(2,6-Dichloropyridin-3-YL)methanamine → 1-(2,6-Dichloro-3-pyridylmethyl)amino-1-methylamino-2-nitroethylene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | (2,6-Dichloropyridin-3-YL)methanamine | HCID 15477284 | — |
| Reactant | N-Methyl-1-(methylsulfanyl)-2-nitroethan-1-amine | HCID 15788612 | — |
| Solvent | Ethanol | HCID 702 | — |
| Product | 1-(2,6-Dichloro-3-pyridylmethyl)amino-1-methylamino-2-nitroethylene | HCID 59896609 | 27.3% |
Reaction Steps
A mixture of 1.2 g (0.007 mole) of (2,6dichloro-3-pyridylmethyl)amine and 1 g (0.007 mole) of 1-methylamino-1-methylthio-2-nitroethane was refluxed in 50 ml of EtOH for 6 hours. After cooling, the reaction mixture was concentrated and the resulting crystals were collected by filtration, washed with CH2Cl2 and a small amount of EtOH in that order and dried. The procedure gave 0.53 g of the title compound as a white powder.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05214152 |
| Source dataset | uspto-grants-1993_05 |
| ORD ID | ord-a8e6b8a12d474ac785b99ef3e44d02a6 |
| Source note | uspto-grants-1993_05 |