HRID24966

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：O=S(=O)(O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F

HCID74483

Perfluorooctanesulfonic acid

C8HF17O3S

HCID11346720

未命名化合物

PRODUCTS

生成物

结构：O=C(C[S+]1CCCC1)c1ccccc1.O=S(=O)([O-])C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F

HCID22564586

未命名化合物

PROCEDURE

实验过程

Compound (III-3) was synthesized by salt exchange of phenacyltetrahydrothiophenium bromide with perfluorooctanesulfonic acid in the same manner as above.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-8f31302e0c1c4635913dc709a1642f4c
来源数据集: uspto-grants-2005_02
DOI: 10.6084/m9.figshare.5104873.v1
专利: US06858370B2
来源说明: uspto-grants-2005_02

反应 SMILES

[Br-].[CH2:2]([S+:11]1[CH2:15][CH2:14][CH2:13][CH2:12]1)[C:3]([C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1)=[O:4].[F:16][C:17]([F:44])([S:40]([OH:43])(=[O:42])=[O:41])[C:18]([F:39])([F:38])[C:19]([F:37])([F:36])[C:20]([F:35])([F:34])[C:21]([F:33])([F:32])[C:22]([F:31])([F:30])[C:23]([F:29])([F:28])[C:24]([F:27])([F:26])[F:25]>>[F:44][C:17]([F:16])([S:40]([O-:43])(=[O:42])=[O:41])[C:18]([F:38])([F:39])[C:19]([F:37])([F:36])[C:20]([F:34])([F:35])[C:21]([F:33])([F:32])[C:22]([F:31])([F:30])[C:23]([F:29])([F:28])[C:24]([F:27])([F:26])[F:25].[CH2:2]([S+:11]1[CH2:15][CH2:14][CH2:13][CH2:12]1)[C:3]([C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1)=[O:4]