Myristyl bromide → 1-(3,5-Dimethoxy-4-n-tetradecanylphenyl)-2-phenylethene

HRID 252325Notes

Reaction equation

HRID 252325 reaction equation
Br[C:2]1[C:7]([O:8][CH3:9])=[CH:6][C:5]([CH:10]=[CH:11][C:12]2[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=2)=[CH:4][C:3]=1[O:18][CH3:19].Br[CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH3:34]>>[CH3:19][O:18][C:3]1[CH:4]=[C:5]([CH:10]=[CH:11][C:12]2[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=2)[CH:6]=[C:7]([O:8][CH3:9])[C:2]=1[CH2:34][CH2:33][CH2:32][CH2:31][CH2:30][CH2:29][CH2:28][CH2:27][CH2:26][CH2:25][CH2:24][CH2:23][CH2:22][CH3:21]

Participants

3

Reactant 2

HCID 8208Myristyl bromideHCID 668426762-Bromo-1,3-dimethoxy-5-(2-phenylethenyl)benzene

Product 1

HCID 668423881-(3,5-Dimethoxy-4-n-tetradecanylphenyl)-2-phenylethene

Procedure

This material was prepared from 2-bromo-1,3-dimethoxy-5-(2-phenylethenyl)benzene and 1-bromo-n-tetradecane by the same procedure as described in Example 15. 1HNMR (CDCl3, ppm): δ 0.91 (m, 6H), 1.29 (m, 22H), 2.65 (m, 2H), 3.90 (s, 6H), 6.73 (s, 2H), 7.10 (s, 2H), 7.26 (m, 1H), 7.36 (m, 2H), 7.52 (m, 2H).

Sources & evidence

ORD record
ord-0a4de70de2fa4438b952fe6570ccd908
Source dataset
uspto-grants-2011_01
Patent number
US07868047B2

Reaction notes

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