(4-Methoxyphenyl)hydrazine → HCID 178492059, compound

HRID 252950Notes

Reaction equation

HRID 252950 reaction equation
[N+:1]([C:4]1[CH:13]=[CH:12][C:11]2[NH:10][CH:9]=[C:8]3[C:14](=[O:23])[N:15]([C:17]4[CH:22]=[CH:21][CH:20]=[CH:19][CH:18]=4)[N:16]=[C:7]3[C:6]=2[CH:5]=1)([O-:3])=[O:2].[CH3:24][O:25]C1C=CC(NN)=CC=1>>[CH3:24][O:25][C:20]1[CH:21]=[CH:22][C:17]([N:15]2[C:14](=[O:23])[C:8]3=[CH:9][NH:10][C:11]4[CH:12]=[CH:13][C:4]([N+:1]([O-:3])=[O:2])=[CH:5][C:6]=4[C:7]3=[N:16]2)=[CH:18][CH:19]=1

Participants

3

Reactant 2

HCID 77023(4-Methoxyphenyl)hydrazineHCID 178515216HCID 178515216, compound

Product 1

HCID 178492059HCID 178492059, compound

Procedure

The title compound was prepared following the procedure for 5a using 4-methoxy phenylhydrazine instead of phenylhydrazine. 1H-NMR (DMSO-d6) δ (ppm): 3.77 (3H, s), 6.89 (1H, dd, J=8.91, 2.37 Hz), 6.95 (2H, m), 7.25 (1H, d, J=2.08 Hz), 7.44 (1H, d, J=8.91 Hz), 8.05 (2H, m), 8.39 (1H, d, J=6.53 Hz). m/z 337.3 (MH+).

Sources & evidence

ORD record
ord-762f92730b4a491c92819542bc44db5a
Source dataset
uspto-grants-2011_01
Patent number
US07872002B2

Reaction notes

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