HCID 178436445, compound → HCID 178436164, compound

HRID 254470Notes

Reaction equation

HRID 254470 reaction equation
[CH2:1]([C:3]1[CH:8]=[CH:7][CH:6]=[C:5](OC)[C:4]=1/[CH:11]=[N:12]/[CH:13]([CH:17]([CH3:19])[CH3:18])[CH:14]([CH3:16])[CH3:15])[CH3:2].[C:20]1([Li])[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=1>>[CH2:1]([C:3]1[C:4](/[CH:11]=[N:12]/[CH:13]([CH:17]([CH3:19])[CH3:18])[CH:14]([CH3:16])[CH3:15])=[C:5]([C:20]2[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=2)[CH:6]=[CH:7][CH:8]=1)[CH3:2]

Participants

3

Reactant 2

HCID 178436445HCID 178436445, compoundHCID 178506676HCID 178506676, compound

Product 1

HCID 178436164HCID 178436164, compound

Procedure

(E)-[1-(3-Ethyl-biphenyl-2-yl)-methylidene]-(1-isopropyl-2-methyl-propyl)-amine was prepared from (E)-[1-(2-ethyl-6-methoxy-phenyl)-methylidene]-(1-isopropyl-2-methyl-propyl)-amine (Example 3 a) and phenyl lithium in analogy to procedure Example 5 a): colourless liquid: MS (ISP): 308.1 ((M+H)+.), 192.9 (((M-((iPr2)2CHNH2))+.), 100%).

Sources & evidence

ORD record
ord-6791b367f4224d81b6ce4c73fa55521a
Source dataset
uspto-grants-2011_01
Patent number
US07875645B2

Reaction notes

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