Carbon tetrabromide → 1-Chloro-2-(2,2-dibromoethenyl)-3-iodobenzene

Participants

Role	Name	HCID	Charge
Reactant	Carbon tetrabromide	HCID 11205	—
Reactant	Triphenylphosphine	HCID 11776	—
Reactant	2-Chloro-6-iodobenzaldehyde	HCID 58951891	—
Product	1-Chloro-2-(2,2-dibromoethenyl)-3-iodobenzene	HCID 58951895	—

Reaction Steps

Chloro-2-(2,2-dibromo-vinyl)-3-iodo-benzene was prepared from 2-chloro-6-iodo-benzaldehyde, carbon tetrabromide and triphenylphosphine in analogy to Example 1d): colourless oil; MS (EI): 425.8 (5%), 423.8 (20%), 421.7 (46%) and 419.7 (18%) (M+), 344.9 (30%), 342.8 (100%) and 340.8 (90%) ([M-Br]+), 263.9 (5%) and 261.9 (25%) ([M-2Br]+), 218.0 (9%), 216.0 (50%) and 214.0 (35%) ([M-Br])+).

Provenance & Evidence

DOI	10.6084/m9.figshare.5104873.v1
Patent number	US07875645B2
Source dataset	uspto-grants-2011_01
ORD ID	ord-fa5ead58a269418f8404862587ab046a
Source note	uspto-grants-2011_01