HuagongsheHuagongshe Chemistry Print Report · For research reference only
Carbon tetrabromide → 1-Chloro-3-(2,2-dibromo-vinyl)-2-ethyl-4-fluoro-benzene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Carbon tetrabromide | HCID 11205 | — |
| Reactant | Triphenylphosphine | HCID 11776 | — |
| Reactant | 3-Chloro-2-ethyl-6-fluoro-benzaldehyde | HCID 58951706 | — |
| Product | 1-Chloro-3-(2,2-dibromo-vinyl)-2-ethyl-4-fluoro-benzene | HCID 58951798 | — |
Reaction Steps
1-Chloro-3-(2,2-dibromo-vinyl)-2-ethyl-4-fluoro-benzene was prepared from 3-chloro-2-ethyl-6-fluoro-benzaldehyde, carbon tetrabromide and triphenylphosphine in analogy to Example 1d): colourless oil; 1H-NMR (CDCl3): 1.15 (3H, t, CH3), 2.72 (2H, q, CH2), 6.90 (1H, dd, ArH), 7.29 (1H, s, CH═CBr2), 7.33 (1H, dd, ArH).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07875645B2 |
| Source dataset | uspto-grants-2011_01 |
| ORD ID | ord-6d12aff7c2e64937ac51fe6b07d7ee84 |
| Source note | uspto-grants-2011_01 |