HuagongsheHuagongshe Chemistry Print Report · For research reference only
Thiodiglycol → 1,5-Bis[3-(3,5-dicyclohexyl-4-hydroxyphenyl)propionyloxy]-3-thiapentane
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Thiodiglycol | HCID 5447 | — |
| Reactant | Methyl 3-(3,5-dicyclohexyl-4-hydroxyphenyl)propionate | HCID 20165247 | — |
| Catalyst | Titanium tetrabutoxide | HCID 21801 | — |
| Solvent | Methanol | HCID 887 | — |
| Product | 1,5-Bis[3-(3,5-dicyclohexyl-4-hydroxyphenyl)propionyloxy]-3-thiapentane | HCID 20165248 | — |
Reaction Steps
0.2 mol of methyl 3-(3,5-dicyclohexyl-4-hydroxyphenyl)propionate, 0.1 mol of 1,5-dihydroxy-3-thiapentane and 2 ml of tetrabutyl titanate are heated for 8 hours at 150° C. as described in Example 2, during which time the methanol forming distills off. After working up, the yield of product is 25.5% of theory.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04699939 |
| Source dataset | uspto-grants-1987_10 |
| ORD ID | ord-54bec84c049b4079904c297c059fe583 |
| Source note | uspto-grants-1987_10 |