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Sodium borohydride → (2,2,5,5-Tetramethylcyclopentyl)methanol
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Sodium borohydride | HCID 4311764 | — |
| 反応物 | Cyclopentanecarboxaldehyde, 2,2,5,5-tetramethyl- | HCID 9793878 | — |
| 溶媒 | Ethanol | HCID 702 | — |
| 生成物 | (2,2,5,5-Tetramethylcyclopentyl)methanol | HCID 13629260 | — |
反応手順
2,2,5,5-Tetramethylcyclopentane-1-carboxaldehyde is dissolved in 95% ethanol and sodium borohydride is added. After 24 hours, the reaction is quenched with 1M HCl and extracted with ether. The extract is washed, dried over MgSO4 and evaporated to yield 2,2,5,5-tetramethyl-1-cyclopentylmethanol.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04701552 |
| 出典データセット | uspto-grants-1987_10 |
| ORD ID | ord-b116a7274c60435fa7d0f6ad586f3ec5 |
| 出典メモ | uspto-grants-1987_10 |