HRID256510

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID87644

2,3,4,5-Tetramethylpyridine

C9H13N

结构：[Li].c1ccc2c(c1)-c1nc-2nc2[nH]c(nc3nc(nc4[nH]c(n1)c1ccccc41)-c1ccccc1-3)c1ccccc21

HCID136122626

未命名化合物

PRODUCTS

生成物

结构：c1ccc2c(c1)-c1nc-2nc2[nH]c(nc3nc(nc4[nH]c(n1)c1ccccc41)-c1ccccc1-3)c1ccccc21

HCID86280045

29H,31H-Phthalocyanine

C32H18N8

PROCEDURE

实验过程

For this preparation, dilithiated lithium phthalocyanine is contacted with (2H)-2,2,6,6-tetramethylpiperidine. The latter was prepared by H-D isotopic exchange between commercially available tetramethylpyridine (TMP) and 2H2O at ambient temperature, followed by a separation of the organic phase and the aqueous phase by ether addition.

WORKUP

后处理

customfollowed by a separation of the organic phase
additionthe aqueous phase by ether addition

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-0172df0db5aa4bbc92d75b5aa16205b4
来源数据集: uspto-grants-1993_11
DOI: 10.6084/m9.figshare.5104873.v1
专利: US05258313
来源说明: uspto-grants-1993_11

反应 SMILES

[Li].[CH:2]1[CH:3]=[CH:4][C:5]2[C:6](=[C:8]3[N:40]=[C:39]4[N:41]=[C:32]([C:33]5[CH:34]=[CH:35][CH:36]=[CH:37][C:38]=54)[N:31]=[C:29]4[NH:30][C:22]([C:23]5[CH:24]=[CH:25][CH:26]=[CH:27][C:28]=54)=[N:21][C:19]4=[N:20][C:12]([C:13]5[CH:14]=[CH:15][CH:16]=[CH:17][C:18]=54)=[N:11][C:10]=2[NH:9]3)[CH:7]=1.CC1C(C)=C(C)C(C)=NC=1>>[CH:3]1[CH:2]=[CH:7][C:6]2[C:5](=[C:10]3[N:11]=[C:12]4[N:20]=[C:19]([C:18]5[CH:17]=[CH:16][CH:15]=[CH:14][C:13]=54)[N:21]=[C:22]4[NH:30][C:29]([C:28]5[CH:27]=[CH:26][CH:25]=[CH:24][C:23]=54)=[N:31][C:32]4=[N:41][C:39]([C:38]5[CH:37]=[CH:36][CH:35]=[CH:34][C:33]=54)=[N:40][C:8]=2[NH:9]3)[CH:4]=1