反应详情

56.53 Grams of 2,3-dichloro-1-propene were added dropwise to a mixture of 25.00 g of cyclohexanone, 75 g of toluene, 100 g of 5% acetic acid and 34.35 g of zinc powder at 45° C., and then the mixture was allowed to react at the same temperature for 3 hours. After the reaction was completed zinc-derived insolubles were filtered off, and the resultant filtrate was subjected to separation. The organic phase was washed with a 7% sodium carbonate aqueous solution and dried over sodium sulfate. The desiccant was filtered off, and then the toluene was distilled off under reduced pressure to give 44.05 g of 1-(2'-chloroallyl)-1-cyclohexanol. The results were as follows.

1. customto react at the same temperature for 3 hours
2. filtrationwere filtered off
3. customthe resultant filtrate was subjected to separation
4. washThe organic phase was washed with a 7% sodium carbonate aqueous solution
5. dry with materialdried over sodium sulfate
6. filtrationThe desiccant was filtered off
7. distillationthe toluene was distilled off under reduced pressure