HuagongsheHuagongshe Chemistry Print Report · For research reference only
Cyclohexanone → Prop-2-enenitrile--ethenylbenzene (1/1)
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Cyclohexanone | HCID 7967 | — |
| Reactant | Isoquinoline | HCID 8405 | — |
| Catalyst | Copper(1+) iodide; Copper(I) iodide; Cuprous iodide; Cuprous iodide (CuI) | HCID 24350 | — |
| Solvent | N-methyl-2-pyrrolidone | HCID 13387 | — |
| Product | Prop-2-enenitrile--ethenylbenzene (1/1) | HCID 62696 | 10% |
Reaction Steps
A solution of 2.0 g. CuI, 1.4 g. isoquinoline (1:1 ratio), 50.0 g. N-methylpyrrolidone solvent, 46.6 g. cyclohexanone and 0.20 g. Lustran SAN 31-1,000 (10% on CuI) was prepared. The resulting coating solution was coated on 7 mil raw PET with number 10 Meyer rod and dried three minutes at 240° F. The coating had very good uniformity and clarity and was gold and blue iridescent and lustrous. The resistivity measured 13-20×107 Ω/sq. The solution after time showed some precipitation, which crystals were redissolved upon reheating.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05259992 |
| Source dataset | uspto-grants-1993_11 |
| ORD ID | ord-3110b0bfc3814e4280160de68cfb5d7b |
| Source note | uspto-grants-1993_11 |