Methyl iodide → 3-(3-(3-Methyl-2-butenyloxy)-1,2,5-thiadiazol-4-yl)-1-methylpyridinium iodide

HRID 256964Notes

Reaction equation

HRID 256964 reaction equation
[CH3:1][I:2].[CH3:3][C:4]([CH3:19])=[CH:5][CH2:6][O:7][C:8]1[C:9]([C:13]2[CH:14]=[N:15][CH:16]=[CH:17][CH:18]=2)=[N:10][S:11][N:12]=1>CC(C)=O>[I-:2].[CH3:3][C:4]([CH3:19])=[CH:5][CH2:6][O:7][C:8]1[C:9]([C:13]2[CH:14]=[N+:15]([CH3:1])[CH:16]=[CH:17][CH:18]=2)=[N:10][S:11][N:12]=1

Participants

4

Reactant 2

HCID 6328Methyl iodideHCID 190753253-(3-(3-Methyl-2-butenyloxy)-1,2,5-thiadiazol-4-yl)pyridine

Product 1

HCID 190753893-(3-(3-Methyl-2-butenyloxy)-1,2,5-thiadiazol-4-yl)-1-methylpyridinium iodide

Reagents, catalysts & solvents 1

HCID 180AcetoneSolvent

Procedure

A mixture of methyl iodide (1 ml, 15 mmol) and 3-(4-(3-methyl-2-butenyloxy)-1, 2,5-thiadiazol-3-yl)pyridine (3 mmol) in acetone (3 ml) was stirred at room temperature for 18 h. The title compound precipitated from the solution and was collected by filtration to yield 0.92 g (79%).

Workup

  1. customThe title compound precipitated from the solution
  2. filtrationwas collected by filtration
  3. customto yield 0.92 g (79%)

Sources & evidence

ORD record
ord-46175e62c42b485da758bb668c60022d
Source dataset
uspto-grants-1993_11
Patent number
US05260311

Reaction notes

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