60976-49-0 → β-D-Glucopyranose, cyclic 3,6-(4,4′,5,5′,6,6′-hexahydroxy[1,1′-biphenyl]-2,2′-dicarboxylate) 1-(3,4,5-trihydroxybenzoate)

HRID 258218Notes

Reaction equation

HRID 258218 reaction equation
[CH:1]1[C:6]([OH:7])=[C:5]([OH:8])[C:4]([OH:9])=[CH:3][C:2]=1[C:10]([O:12][C@@H:13]1[O:18][C@@H:17]2[CH2:19][O:20][C:21]([C:23]3[CH:24]=[C:25]([OH:43])[C:26]([OH:42])=[C:27]([OH:41])[C:28]=3[C:29]3[C:34]([OH:35])=[C:33]([OH:36])[C:32]([OH:37])=[CH:31][C:30]=3[C:38]([O:40][C@H:15]3[C@@H:16]2[O:44]C(C2[C@H]4C5C(C([O:65][C@@H:14]13)=O)=CC(O)=C(O)C=5O[C@](O)(C4(O)O)C(=O)C=2)=O)=[O:39])=[O:22])=[O:11]>O>[CH:1]1[C:2]([C:10]([O:12][C@@H:13]2[O:18][C@@H:17]3[CH2:19][O:20][C:21]([C:23]4[CH:24]=[C:25]([OH:43])[C:26]([OH:42])=[C:27]([OH:41])[C:28]=4[C:29]4[C:34]([OH:35])=[C:33]([OH:36])[C:32]([OH:37])=[CH:31][C:30]=4[C:38]([O:40][C@@H:15]([C@@H:16]3[OH:44])[C@H:14]2[OH:65])=[O:39])=[O:22])=[O:11])=[CH:3][C:4]([OH:9])=[C:5]([OH:8])[C:6]=1[OH:7]

Participants

3

Reactant 1

HCID 300149760976-49-0

Product 1

HCID 73568β-D-Glucopyranose, cyclic 3,6-(4,4′,5,5′,6,6′-hexahydroxy[1,1′-biphenyl]-2,2′-dicarboxylate) 1-(3,4,5-trihydroxybenzoate)

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

Hydrolysis of geraniin in boiling water, gallic acid ellagic acid and corilagin were produced, which were identified by thin-layer co-chromatography with authentic samples.

Sources & evidence

ORD record
ord-09226a8287944f7e9c6847f7670c5b41
Source dataset
uspto-grants-1993_11
Patent number
US05266319

Reaction notes

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